Pine Oil

Pine Oil

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Pine OIl

Company

REFLECTA LAB SUPPLIES

SECTION 2 Pine Oil – HAZARDS IDENTIFICATION GHS-Classification

Flammable liquids, Category 4

Skin irritation, Category 2

Eye irritation, Category 2A

Skin sensitisation, Category 1

Aspiration hazard, Category 1

GHS-Labelling

Symbol(s) :

Signal word : Danger

Pine Oil

Hazard statements : H227: Combustible liquid.

H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.

H317: May cause an allergic skin reaction.

H319: Causes serious eye irritation.

Precautionary statements : P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P280: Wear protective gloves/ eye protection/ face protection.

P301 + P310: IF SWALLOWED: Immediately call a POISON

CENTER or doctor/ physician.

P302 + P352: IF ON SKIN: Wash with plenty of soap and water.

P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for

several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing.

P331: Do NOT induce vomiting.

Carcinogenicity:

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature : Fragrance for consumer product

Hazardous components

Component	CAS-No.
Oils, pine	8002-09-3, 8000-41-7

Pine Oil

SECTION 4. Pine Oil – FIRST AID MEASURES

First aid procedures

Inhalation : Remove from exposure site to fresh air and keep at rest. If victim is unconscious, remove foreign bodies from the mouth. If victim has

stopped breathing, give artificial respiration. Obtain medical advice.

Skin contact : Remove contaminated clothes. Wash thoroughly with water (and soap). Contact physician if symptoms persist.

Eye contact : Flush immediately with water for at least 15 minutes. Contact physician if symptoms persist.

Ingestion : Rinse mouth with water and obtain medical advice.

SECTION 5. FIREFIGHTING MEASURES

Flammable properties

Flash point : 162 °F (72 °C)

Fire fighting

Suitable extinguishing media : Use water spray, dry chemical, carbon dioxide or appropriate foam. Protective equipment and precautions for firefighters

Special protective equipment for firefighters

: Wear NIOSH approved self-contained breathing apparatus and full protective clothing when fighting fires involving chemicals. Use water spray to cool containers exposed to fire.

Pine Oil

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Avoid inhalation and contact with skin and eyes. A self-contained breathing apparatus is recommended in case of a major spill.

Environmental precautions : Keep away from drains, surface- and groundwater and soil.

Methods for containment / : Clean up spillage promptly. Remove ignition sources. Provide Methods for cleaning up adequate ventilation. Avoid excessive inhalation of vapours. Gross spillages should be contained by use of sand or inert powder

and disposed of according to the local regulations.

SECTION 7. Pine Oil – HANDLING AND STORAGE

Handling

Advice on protection against fire and explosion

: Avoid excessive inhalation of concentrated vapors. Follow good manufacturing practices for housekeeping and personal hygiene. Wash any exposed skin immediately after any chemical contact, before breaks and meals, and at the end of each work period.

Contaminated clothing and shoes should be thoroughly cleaned before re-use.

If appropriate, procedures used during the handling of this material should also be used when cleaning equipment or removing residual chemicals from tanks or other containers, especially when steam or hot water is used, as this may increase vapor concentrations in the

workplace air. Where chemicals are openly handled, access should be restricted to properly trained employees.

Keep all heated processes at the lowest necessary temperature in order to minimize emissions of volatile chemicals into the air.

: Keep away from ignition sources and naked flame.

Requirements for storage areas and containers

Pine Oil

: Store in a cool, dry, ventilated area away from heat sources. Keep containers upright and tightly closed when not in use.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters

Components	Listed by	Value type	Exposure limit(s)
3-Cyclohexene-1- methanol, .alpha.,.alpha.,4- trimethyl	USA. ACGIH Threshold Limit Values (TLV)	8-hour, time-weighted average	20 ppm
Cyclohexene, 1- methyl-4-(1- methylethenyl)-, Cyclohexene, 1- methyl-4-(1- methylethenyl)-, (4R)-, Cyclohexene, 1-methyl-4-(1- methylethenyl)-, (4S)-	USA. Workplace Environmental Exposure Levels (WEEL)	8-hr TWA	30 ppm

Engineering measures

Engineering measures : Where feasible, isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under

negative air pressure relative to the rest of the plant.

Where feasible, use closed systems to transfer and process this

material

Personal protective equipment

Eye protection : Use tight-fitting goggles, face shield or safety glasses with side

Pine Oil

shields if eye contact might occur.

Hand protection : Avoid skin contact. Use chemically resistant gloves.

Respiratory protection : Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation,

including places where this material is openly weighed or measured.

In addition, use general dilution ventilation of the work area to

eliminate or reduce possible worker exposures.

No respiratory protection is required during normal operations in a

workplace where engineering controls such as adequate ventilation,

etc. are sufficient.

If engineering controls and safe work practices are not sufficient, an

approved, properly fitted respirator with organic vapor cartridges or

canisters and particulate filters should be used:

a)while engineering controls and appropriate safe work practices

and/or procedures are being implemented; or

b)during short term maintenance procedures when engineering

controls are not in normal operation or are not sufficient; or

c)if normal operational workplace vapor concentration in the air is

increased due to heat ;

d)during emergencies; or

e)if engineering controls and operational practices are not sufficient

to reduce airborne concentrations below an established occupational

exposure limit.

Hygiene measures : To the extent deemed appropriate, implement pre-placement and regularly scheduled ascertainment of symptoms and spirometry

testing of lung function for workers who are regularly exposed to

this material.

To the extent deemed appropriate, use an experienced air sampling

expert to identify and measure volatile chemicals that could be

present in the workplace air to determine potential exposures and to

ensure the continuing effectiveness of engineering controls and

operational practices to minimize exposure.

Pine Oil

Protective measures : In December 2003, the National Institute for Occupational Safety and Health (“NIOSH”) published an Alert on preventing lung

disease in workers who use or make flavorings [NIOSH Publication

Number 2004-110].

In August 2004, the United States Flavor and Extract Manufacturers

Association (FEMA) issued a report entitled “Respiratory Safety in

the Flavor Manufacturing Workplace”.

Both of these reports provide recommendations for reducing

employee exposure and for medical surveillance in the workplace.

The recommendations in these reports are generally applicable to the

use of any chemical in the workplace and you are strongly urged to

review both of these reports.

The report published by FEMA also contains a list of “high priority”

chemicals. If any of these chemicals are present in this product at a

concentration >= 1.0% due to an intentional addition by IFF, the

chemical(s) will be identified in this safety data sheet.

SECTION 9. Pine Oil – PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Physical state : liquid

Appearance : CLEAR LIQUID

Colour : colorless to pale yellow

Odour : conforms to standard

Safety data

Flash point : 162 °F (72 °C)

Vapour pressure : 5.33 hPa (5.33 hPa)

Note: Calculated

Pine Oil

Relative density (20 °C) : 0.9240 – 0.9310

SECTION 10. STABILITY AND REACTIVITY Conditions to avoid : Remarks: Direct sources of heat.

Chemical stability : Remarks: Presents no significant reactivity hazard, by itself or in contact with water. Avoid contact with strong acids, alkali or

oxidizing agents.

Hazardous decomposition products : Note: Carbon monoxide and unidentified organic compounds may be formed during combustion.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : Acute toxicity estimate

Dose: 2,027 mg/kg

Method: Calculation method

Acute oral toxicity (Component) : Component: 98-55-5

LD50 Rat

Dose: 4,300 mg/kg

Method: OECD Test Guideline 401

Remarks: RIFM

Component: 138-86-3

LD50 Rat

Dose: 5,300 mg/kg

Component: 586-62-9

LD50 Rat

Dose: 3,840 mg/kg

Pine Oil

Remarks: RIFM

Component: 562-74-3

LD50 Rat

Dose: 1,300 mg/kg

Remarks: RIFM

Component: 470-82-6

LD50 Rat

Dose: 2,480 mg/kg

Remarks: Supplier

Acute dermal toxicity : Acute toxicity estimate Dose: 3,733 mg/kg

Method: Calculation method

Acute dermal

toxicity (Component)

: Component: 98-55-5

LD50 Rabbit

Dose: > 3,000 mg/kg

Method: OECD Test Guideline 402

Component: 138-86-3

LD50 Rabbit

Dose: > 5,000 mg/kg

Component: 586-62-9

LD50 Rabbit

Dose: > 5,000 mg/kg

Component: 562-74-3

LD50 Rabbit

Dose: 2,500 mg/kg

Component: 470-82-6

LD50 Rabbit

Dose: > 5,000 mg/kg

Pine Oil

Skin irritation (Component) : Component: 98-55-5 Rabbit

Result: Skin irritation

Method: OECD Test Guideline 404

Exposure time: 24 h

Component: 138-86-3

Rabbit

Result: Skin irritation

Exposure time: 24 h

Test substance:(undiluted)

human

Result: No skin irritation

Method: closed patch test

Exposure time: 48 h

Component: 586-62-9

human

Result: No skin irritation

Method: closed patch test

Exposure time: 48 h

Rabbit

Result: No skin irritation

Exposure time: 24 h

Component: 562-74-3

Rabbit

Result: Skin irritation

Exposure time: 24 h

Component: 470-82-6

Rabbit

Result: No skin irritation

Exposure time: 24 h

Eye irritation(Component) : Component: 98-55-5 Rabbit

Pine Oil

Result: Eye irritation

Method: OECD Test Guideline 405

Exposure time: 72 h

Sensitisation (Component) : Component: 98-55-5

LLNA Rat

Result: causes no sensitization

Method: OECD Test Guideline 429

Component: 138-86-3

LLNA Mouse

Result: Causes sensitisation.

Test substance: 22% in ethanol/DEP (75:25)

maximisation study human

Result: causes no sensitization

Test substance: 20% in petrolatum

Component: 586-62-9

maximisation study human

Result: Did not cause sensitisation on laboratory animals.

Test substance: 20% in petrolatum

Component: 562-74-3

human

Result: causes no sensitization

Repeated dose

toxicity(Component)

: Component: 98-55-5

OralRat

NOEL: > 314 mg/kg

Method: OECD Test Guideline 408

Remarks: No adverse effect has been observed in chronic toxicity tests.

Component: 138-86-3

Component: 586-62-9

Carcinogenicity (Component) :

Pine Oil

Component: 562-74-3 Component: 98-55-5

SECTION 12. Pine Oil – ECOLOGICAL INFORMATION

Component:

98-55-5 alpha-TerpineolToxicity to fish:

semi-static test LC50

Species: Brachydanio rerio (zebrafish)

Dose: 70 mg/l

Exposure time: 96 h

Method: OECD Test Guideline 203

Information taken from reference works and the

literature.

Toxicity to daphnia and other aquatic invertebrates:

static test EC50

Species: Daphnia magna (Water flea)

Dose: 73 mg/l

Exposure time: 48 h

Method: OECD Test Guideline 202

Information taken from reference works and the

literature.

Toxicity to algae:

static testEC50

Species: Pseudokirchneriella subcapitata (aglae)

Dose: 68 mg/l

Exposure time: 72 h

Method: OECD Test Guideline 201

Information taken from reference works and the

literature.

Toxicity to algae:

static testNOEC

Species: Pseudokirchneriella subcapitata (aglae)

Pine Oil

Dose: 3.9 mg/l

Exposure time: 72 h

Method: OECD Test Guideline 201

Information taken from reference works and the

literature.

Toxicity to bacteria:

static test NOEC

Species: activated sludge

Dose: 25.7 mg/l

Method: OECD Test Guideline 310

138-86-3 Dipentene Toxicity to fish:

LC50

Species:

Dose: 0.702 mg/l

Exposure time: 96 h

586-62-9 Terpinolene Toxicity to fish:

LC50

Species:

Dose: 1.21 mg/l

Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates:

EC50

Species:

Dose: 1.38 mg/l

Exposure time: 48 h

Toxicity to daphnia and other aquatic invertebrates:

EC50

Species:

Dose: 2.55 mg/l

Exposure time: 48 h

Pine Oil

562-74-3 4-Terpineol Toxicity to daphnia and other aquatic invertebrates: static test EC50

Species: Daphnia magna (Water flea)

Dose: 97 mg/l

Exposure time: 48 h

RIFM

SECTION 13. Pine Oil – DISPOSAL CONSIDERATIONS

Contaminated packaging : Place material into sealed containers and dispose of in accordance with local, state and federal regulations.

SECTION 14. TRANSPORT INFORMATION

DOT Proper shipping name : Combustible liquid, n.o.s. (DIPENTENE)

UN number : 1993

Class : CBL

Packing group : III

Emergency Response : 128

Guidebook Number

DOT NON-BULK Not dangerous goods

IATA UN number : 3082

Description of the goods : ENVIRONMENTALLY HAZARDOUS

SUBSTANCE, LIQUID, N.O.S.

(DIPENTENE)

Class : 9

Packing group : III

ICAO-Labels : 9

Pine Oil

IMDG UN number : 3082

Description of the goods : ENVIRONMENTALLY HAZARDOUS

SUBSTANCE, LIQUID, N.O.S.

(DIPENTENE)

Class : 9

Packing group : III

IMDG-Labels : 9

EmSNumber 1 : F-A

EmSNumber 2 : S-F

Marine pollutant : yes

(DIPENTENE)

SECTION 15. REGULATORY INFORMATION

SARA 311/312 Hazards : Fire Hazard

Acute Health Hazard

Reportable Quantity :

HMIS Classification : Health hazard: 1

Flammability: 2

Physical and chemical hazards: 0

SECTION 16. Pine Oil – OTHER INFORMATION

All reasonable efforts were exercised to compile this SDS in accordance with GHS SANS 10234. The SDS provides information regarding the health, safety and environmental hazards, at the date of issue, to facilitate the safe receipt, use and handling of the product in the workplace. RLS cannot anticipate or control all conditions under which the product may be handled, used and received in the workplace, it remains the obligation of each user, receiver or handler to, prior to usage, review this SDS in the context within which the product will be received, handled or used in the workplace. The user, handler or receiver must ensure that the necessary mitigating measures are in place as regards health and safety. This does not substitute the need or requirement for any relevant risk assessments to be conducted. It further remains the responsibility of the receiver, handler or user to communicate such information to all relevant parties that may be involved in the receipt, use or handling of the product. Although all reasonable efforts were exercised in the compilation of this SDS, RLS does not expressly warrant the accuracy or assume any liability for the incompleteness of the information contained herein or any advice given. The product is sold and risk passes in accordance with the specific terms and conditions of sale

DisclaimerThe information stated above is considered to be correct, but does not claim to be inclusive and shall only be used as a guideline. The information provided by this document is confirmed by our continuous updating of knowledge and adheres to the products appropriate safety precautions. It does not represent any guarantee of the product’s
properties. RLS Chemicals and its Associates shall not be held accountable for any damage’s consequent of handling the above product.

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